[(CrGe9)Cr2(CO)13]4−: A disubstituted case of ten-vertex closo cluster with spherical aromaticity

Authors: 
Ya-Shan Huang, Dandan Chen, Jun Zhu, Zhong-Ming Sun
Journal: 
Chin. J. Chem.
Year: 
2021
Volume: 
32
FirstPage-LastPage: 
In Press
TOC: 
Abstract: 

We report the first disubstituted hetero-ten-vertex closo cluster [(CrGe9)Cr2(CO)13]4- with three adjacent Cr(CO)n units adopting both η5 and η1 coordination modes, which was synthesized through the reaction of “KGe1.67” with (MeCN)3Cr(CO)3 and Cr(CO)6 in ethylenediamine (en) solution. In contrast to the η1-Cr atoms forming localized two-center two-elelctron (2c-2e) Cr-Ge bonds, the hetero atom η5-Cr exhibits versatile bonding mechanisms including three 5c-2e and five 8c-2e delocalized bonds which account for Hückel aromaticity. Intricate multi-center bonding patterns delineate the multiple local σ-aromatic characters of the title cluster displaying explicit spherical aromaticity.

https://www.sciencedirect.com/science/article/pii/S1001841721006124

Doi: 
10.1016/j.cclet.2021.08.038