radical

A Bis(silylene)pyridine Pincer Ligand Can Stabilize Mononuclear Manganese(0) Complexes: Facile Access to Isolable Analogues of the Elusive d7-Mn(CO)5 Radical

Using the potentially tridentate N,N’-bis(N-heterocyclic silylene)pyridine [SiNSi] pincer-type ligand, 2,6-N,N’-diethyl-bis[N,N’-di-tert-butyl(phenylamidinato)silylene] diaminopyridine, led to the first isolable bis(silylene)pyridine-stabilized manganese(0) complex, {к3-[SiNSi]Mn(dmpe)} 4 (dmpe = (Me2P)2C2H4), which represents an isolobal 17 VE analogue of the elusive Mn(CO)5 radical.

Electrochemical Migratory Cyclization of N-acylsulfonamides

Benzoxathiazine dioxide, as a bioisostere of the clinically widely used diazoxide, exhibits interesting biological activity. However, limited success has been achieved in terms of its concise and direct synthesis. We report herein a facile electrochemical migratory cyclization of N -acylsulfonamides to access a diverse array of benzoxathiazine dioxides. The inclusion of electrochemistry is crucial for realizing such a novel transformation, which is substantiated both by the experiments and density-functional-theory calculations.

Predicting Dinitrogen Activation by Five-Electron Boron-Centered Radicals

Due to the high bond dissociation energy (945 kJ mol–1) and the large highest occupied molecular orbital–lowest unoccupied molecular orbital (HOMO–LUMO) gap (10.8 eV), dinitrogen activation under mild conditions is extremely challenging. On the other hand, the conventional Haber–Bosch ammonia synthesis under harsh conditions consumes more than 1% of the world’s annual energy supply. Thus, it is important and urgent to develop an alternative approach for dinitrogen activation under mild conditions.

Antiaromaticity-Promoted Radical Stability in α-Methyl Heterocyclics

Aromaticity is a fundamental and important concept in chemistry, and usually, the enhancement of aromaticity brings additional thermodynamic stability to a compound. Moreover, since radicals can act as intermediates in chemical reactions, they have attracted considerable attention from both experimental and theoretical chemists for a long time. However, it remains unclear whether there is a relationship between the thermodynamic stability of cyclic planar radicals and their aromaticity.